1,245 research outputs found

    NewsPad: Designing for Collaborative Storytelling in Neighborhoods

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    This paper introduces design explorations in neighborhood collaborative storytelling. We focus on blogs and citizen journalism, which have been celebrated as a means to meet the reporting needs of small local communities. These bloggers have limited capacity and social media feeds seldom have the context or readability of news stories. We present NewsPad, a content editor that helps communities create structured stories, collaborate in real time, recruit contributors, and syndicate the editing process. We evaluate NewsPad in four pilot deployments and find that the design elicits collaborative story creation.Comment: NewsPad: designing for collaborative storytelling in neighborhoods. In Proceedings of the extended abstracts of the 32nd annual ACM conference on Human factors in computing systems (CHI EA 2014

    Surface tension of electrolytes: Hydrophilic and hydrophobic ions near an interface

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    We calculate the ion distributions around an interface in fluid mixtures of highly polar and less polar fluids (water and oil) for two and three ion species. We take into account the solvation and image interactions between ions and solvent. We show that hydrophilic and hydrophobic ions tend to undergo a microphase separation at an interface, giving rise to an enlarged electric double layer. We also derive a general expression for the surface tension of electrolyte systems, which contains a negative electrostatic contribution proportional to the square root of the bulk salt density. The amplitude of this square-root term is small for hydrophilic ion pairs, but is much increased for hydrophilic and hydrophobic ion pairs. For three ion species including hydrophilic and hydrophobic ions, we calculate the ion distributions to explain those obtained by x-ray reflectivity measurements.Comment: 8 figure

    Thermodynamics of nano-cluster phases: a unifying theory

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    We propose a unifying, analytical theory accounting for the self-organization of colloidal systems in nano- or micro-cluster phases. We predict the distribution of cluter sizes with respect to interaction parameters and colloid concentration. In particular, we anticipate a proportionality regime where the mean cluster size grows proportionally to the concentration, as observed in several experiments. We emphasize the interest of a predictive theory in soft matter, nano-technologies and biophysics.Comment: 4 pages, 1 figur

    Minimal Bending Energies of Bilayer Polyhedra

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    Motivated by recent experiments on bilayer polyhedra composed of amphiphilic molecules, we study the elastic bending energies of bilayer vesicles forming polyhedral shapes. Allowing for segregation of excess amphiphiles along the ridges of polyhedra, we find that bilayer polyhedra can indeed have lower bending energies than spherical bilayer vesicles. However, our analysis also implies that, contrary to what has been suggested on the basis of experiments, the snub dodecahedron, rather than the icosahedron, generally represents the energetically favorable shape of bilayer polyhedra

    Electrostatic Interactions of Asymmetrically Charged Membranes

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    We predict the nature (attractive or repulsive) and range (exponentially screened or long-range power law) of the electrostatic interactions of oppositely charged and planar plates as a function of the salt concentration and surface charge densities (whose absolute magnitudes are not necessarily equal). An analytical expression for the crossover between attractive and repulsive pressure is obtained as a function of the salt concentration. This condition reduces to the high-salt limit of Parsegian and Gingell where the interaction is exponentially screened and to the zero salt limit of Lau and Pincus in which the important length scales are the inter-plate separation and the Gouy-Chapman length. In the regime of low salt and high surface charges we predict - for any ratio of the charges on the surfaces - that the attractive pressure is long-ranged as a function of the spacing. The attractive pressure is related to the decrease in counter-ion concentration as the inter-plate distance is decreased. Our theory predicts several scaling regimes with different scaling expressions for the pressure as function of salinity and surface charge densities. The pressure predictions can be related to surface force experiments of oppositely charged surfaces that are prepared by coating one of the mica surfaces with an oppositely charged polyelectrolyte

    Effect of dipolar moments in domain sizes of lipid bilayers and monolayers

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    Lipid domains are found in systems such as multi-component bilayer membranes and single component monolayers at the air-water interface. It was shown by Andelman et al. (Comptes Rendus 301, 675 (1985)) and McConnell et al. (Phys. Chem. {\bf 91}, 6417 (1987)) that in monolayers, the size of the domains results from balancing the line tension, which favors the formation of a large single circular domain, against the electrostatic cost of assembling the dipolar moments of the lipids. In this paper, we present an exact analytical expression for the electric potential, ion distribution and electrostatic free energy for different problems consisting of three different slabs with different dielectric constants and Debye lengths, with a circular homogeneous dipolar density in the middle slab. From these solutions, we extend the calculation of domain sizes for monolayers to include the effects of finite ionic strength, dielectric discontinuities (or image charges) and the polarizability of the dipoles and further generalize the calculations to account for domains in lipid bilayers. In monolayers, the size of the domains is dependent on the different dielectric constants but independent of ionic strength. In asymmetric bilayers, where the inner and outer leaflets have different dipolar densities, domains show a strong size dependence with ionic strength, with molecular-sized domains that grow to macroscopic phase separation with increasing ionic strength. We discuss the implications of the results for experiments and briefly consider their relation to other two dimensional systems such as Wigner crystals or heteroepitaxial growth.Comment: 13 pages, 5 figues in eps Replaced with new version, one citation added and a few statements corrected. The results of the paper are unchange

    Irreversibility in response to forces acting on graphene sheets

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    The amount of rippling in graphene sheets is related to the interactions with the substrate or with the suspending structure. Here, we report on an irreversibility in the response to forces that act on suspended graphene sheets. This may explain why one always observes a ripple structure on suspended graphene. We show that a compression-relaxation mechanism produces static ripples on graphene sheets and determine a peculiar temperature TcT_c, such that for T<TcT<T_c the free-energy of the rippled graphene is smaller than that of roughened graphene. We also show that TcT_c depends on the structural parameters and increases with increasing sample size.Comment: 4 pages, 4 Figure

    Universal reduction of pressure between charged surfaces by long-wavelength surface charge modulation

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    We predict theoretically that long-wavelength surface charge modulations universally reduce the pressure between the charged surfaces with counterions compared with the case of uniformly charged surfaces with the same average surface charge density. The physical origin of this effect is the fact that surface charge modulations always lead to enhanced counterion localization near the surfaces, and hence, fewer charges at the midplane. We confirm the last prediction with Monte Carlo simulations.Comment: 8 pages 1 figure, Europhys. Lett., in pres

    Long-term storage of table grape cultivars and the use of liquid-S02 and solid -in-package-S02 generators

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    Danugue, Waltham Cross, Alphonse Lavallee and Sultanina cvs. of tablegrapes were kept for several weeks in cold storage. To control rots, liquid- orsolid-SO2 generators were used. The appropriate method of SO2 application has tobe chosen according to the cultivar. Of the cvs. examined, Alphonse Lavallee wasthe most suitable for long-term storage. Sultanina had a more restricted storageperiod because of its susceptibility to decay and SO2 injury, Waltham Cross sufferedfrom berry browning, and Danugue from split berries.Langfristige Lagerung von Tafeltraubensorten unter Verwendung von Flüssig- undFest-S02-SpendernTafeltrauben der Sorten Danugue, Waltham Cross, Alphonse Lavellee und Sultanina wurden mehrere Wochen lang kühl gelagert. Um Fäulnisvorgänge zu unterbinden, wurden den Kartons SO2-Spender auf flüssiger oder fester Basis beigepackt. Die Methode der SO2-Anwendung -muß der jeweiligen Traubensorte angepaßt werden. Von den geprüften Sorten eignete sich Alphonse Lavallee am besten für die langfristige Lagerung. Sultanina war wegen ihrer Anfälligkeit gegen Fäulnis und Schädigung durch SO2 nur beschränkt lagerungsfähig. Bei Waltham Cross traten in größerem Umfang gebräunte, bei Danugue geplatzte Beeren auf
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